High Levels of Arsenic Found in Groundwater Near Fracking Sites
A new report finds poisonous arsenic contamination in Texas occurring in close proximity to natural gas extraction
A new study out of the University of
Texas in Arlington finds high levels of arsenic in groundwater near
fracking sites. Pictured: natural gas rig outside of Shreveport,
Louisiana.
Image: Flickr/Daniel Foster
A recently published
study
by researchers at the University of Texas at Arlington found elevated
levels of arsenic and other heavy metals in groundwater near natural gas
fracking sites in Texas’ Barnett Shale.
While the findings are far from conclusive, the study provides further
evidence tying fracking to arsenic contamination. An internal
Environmental Protection Agency PowerPoint presentation
recently obtained by the Los Angeles Times warned that wells near Dimock, Pa., showed
elevated levels of arsenic in the groundwater. The EPA also
found arsenic in groundwater near fracking sites in Pavillion, Wyo., in 2009 — a study the agency
later abandoned.
ProPublica talked with Brian Fontenot, the paper’s lead author, about
how his team carried out the study and why it matters. (Fontenot and
another author, Laura Hunt, work for the EPA in Dallas, but they
conducted the study on their own time in collaboration with several UT
Arlington researchers.) Here’s an edited version of our interview:
What led you guys to do the study?
We were sort of talking around lunch one day, and came up with the idea of actually going out and testing
water
in the Barnett Shale. We’d heard all the things that you see in the
media, all the sort of really left-wing stuff and right-wing stuff, but
there weren’t a whole lot of answers out there in terms of an actual
scientific study of water in the Barnett Shale. Our main intent was to
bring an unbiased viewpoint here — to just look at the water, see if we
could find anything, and report what we found.
What kind of previous studies had been done in this vein?
The closest analog that I could find to our type of study are the things
that have been done in the Marcellus Shale, with Rob Jackson’s group
out at Duke University. Ours is set up very similarly to theirs in that
we went out to private landowners’ wells and sampled their water wells
and assayed them for various things. We decided to go with a list of
chemicals thought to be included in hydraulic fracturing that was
actually released in a congressional report. Our plan was to sample
everyone’s water that we could, and then go through that list of these
potential chemical compounds within the congressional list.
How did you do it?
We were able to get a press release put out from UT Arlington that went
into the local newspapers that essentially called for volunteers to be
participants in the study. For being a participant, you would get free
water testing, and we would tell them our results. We were upfront with
everyone about, you know, we don’t have a bias, we’re not anti-industry,
we’re not pro-industry. We’re just here to finally get some scientific
data on this subject. And we had a pretty overwhelming response.
From there we chose folks that we would be able to get to. We had to
work on nights and weekends, because we had an agreement with EPA to
work on this study outside of work hours. So we spent quite a few
weekend days going out to folks who had responded to our call and
sampling their water. But that wasn’t quite enough. We also had to get
samples from within the Barnett Shale in areas where fracking was not
going on, and samples from outside the Barnett Shale where there’s no
fracking going on, because we wanted to have those for reference
samples. For those samples we went door to door and explained to folks
what our study was about.
We have people that were pro-industry that wanted to participate in this
study to help out — saying, you know, ‘You’re not going to find
anything and I’m going to help you prove it.’ And we also had folks that
were determined to find problems. We have the whole gamut of folks
represented in our study.
We would take a
water
well, and we would go directly to the head, the closest we could get to
the actual water source coming out of the ground, and we would purge
that well for about 20 minutes. That ensures that you’re getting fresh
water from within the aquifer. So we didn’t take anything from the tap,
and nothing that had been through any kind of filtration system. This
was as close to the actual groundwater as we could get. We took some
measurements, and then we took several samples back to UT Arlington for a
battery of chemistry analyses. That’s where we went through and looked
for the various volatile organic compounds and heavy metals and
methanols and alcohols and things like that.
What did you find?
We found that there were actually quite a few examples of elevated
constituents, such as heavy metals, the main players being arsenic,
selenium and strontium. And we found each of those metals at levels that
are above EPA’s maximum contaminate limit for drinking water.
These heavy metals do naturally occur in the groundwater in this region.
But we have a historical dataset that points to the fact that the
levels we found are sort of unusual and not natural. These really high
levels differ from what the groundwater used to be like before fracking
came in. And when you look at the location of the natural gas wells, you
find that any time you have water wells that exceed the maximum
contaminate limit for any of these heavy metals, they are within about
three kilometers of a natural gas well. Once you get a private water
well that’s not very close to a natural gas well, all of these heavy
metals come down. But just because you’re close to a natural gas well
does not mean you’re guaranteed to have elevated contaminate levels. We
had quite a few samples that were very close to natural gas wells that
had no problems with their water at all.
We also found a few samples that had measureable levels of methanol and
ethanol, and these are two substances that don’t naturally occur in
groundwater. They can actually be created by bacterial interactions
underwater, but whenever methanol or ethanol occur in the environment,
they’re very fleeting and transient. So for us to be able to actually
randomly take a grab sample and detect detectable methanol and ethanol —
that implies that there may be a continuous source of this.
You found levels of arsenic in areas with fracking that were
almost 18 times higher than in areas without fracking or in the
historical data. What would happen to someone who drank that water?
Arsenic is a pretty well-known poison. If you experience a lot of
long-term exposure to arsenic, you get a lot of different risks, like
skin damage, problems with the circulatory system or even an increased
risk of
cancer.
The levels that we found would not be a lethal dose, but they’re
certainly levels that you would not want to be exposed to for any
extended period of time.
What about the other stuff you found?
The heavy metals are a little bit different because they are known to be
included in some fracking recipes. But they’re also naturally occurring
compounds. We think the problem is that they’re becoming concentrated
at levels that aren’t normal as a result of some aspect of natural gas
extraction.
It’s not necessarily that we’re saying fracking fluid getting out. We
don’t have any evidence of that. But there are many other steps
involved, from drilling the hole to getting the water back out. A lot of
these can actually cause different scenarios whereby the naturally
occurring heavy metals will become concentrated in ways they normally
wouldn’t. For example, if you have a private water well that’s not kept
up well, you’ll have a scale of rust on the inside. And if someone were
to do a lot of drilling nearby, you may find some pressure waves or
vibrations that would cause those rust particles to flake out into the
water. Arsenic is bound up inside that rust, and that can actually
mobilize arsenic that would never be in the water otherwise.
Methanol and ethanol are substances that should not be very easy to find
in the groundwater naturally. We definitely know that those are on the
list of things that are known to be in hydraulic fracturing fluid. But
we were unable to actually sample any hydraulic fracturing fluid, so we
can’t make any claims that we have evidence fluids got into the
water.
Have you talked with the homeowners whose wells you sampled?
We have shown those homeowners the results. I think most of the folks
that had high levels of heavy metals were not necessarily surprised.
You hear so much I think maybe they were expecting it to come back with
something even more extreme than that. I don’t want to say they were
relieved, but I think they all sort of took the news in stride and
realized, OK, well, as a private well owner there’s no state or federal
agency that provides any kind of oversight or regulation, so it’s
incumbent on that well owner to get testing done and get any kind of
remediation.
Do you think fracking is responsible for what you found?
Well, I can’t say we have a
smoking
gun. We don’t want the public to take away from this that we have
pegged fracking as the cause of these issues. But we have shown that
these issues do occur in close relation, geographically, to natural gas
extraction. And we have this historical database from pretty much the
same exact areas that we sampled that never had these issues until the
onset of all the fracking. We have about 16,000 active wells here in the
Barnett Shale, and that’s all popped up in about the last decade, so
it’s been a pretty dramatic increase.
We noticed that when you’re closer to a well, you’re more likely to have
a problem, and that today’s samples have problems, while yesterday’s
samples before the fracking showed up did not. So we think that the
strongest argument we can say is that this needs more research.
From ProPublica.org (find the original story here); reprinted with permission.